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Question

Which of the following is most acidic?

A
Benzyl alcohol
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B
Cyclohexanol
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C
Phenol
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D
m - Chlorophenol
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Solution

The correct option is D m - Chlorophenol
Halogens have both +R and -I effect, but the -I effect predominates over the +R effect. Therefore, m-Chlorophenols most acidic due to electron withdrawing -Cl group. Alcohols are less acidic than phenol.

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