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Question

Which of the following is most basic?
(Write 1 if I is the answer)

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Solution

The basicity order is III>II>I

Compoun (III) is attached with I effect of Electron withdrawing group but lone pair on N-atom is available and EWD group is far away from N-atom.

In case of (I), EWD group decrease the basicity through I effect from two side and compound (II) +I effect of one methyl group attached to the N-atom.

So (II) is more basic than (I)

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