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Periodic Properties

Which of the ...

Question

Which of the following is not a nitro derivative?

C_{6} H_{5} N O_{2}

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C H_{3} C H_{2} O N O

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(C H_{3})_{2} - C H - N O_{2}

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C_{6} H_{4} (O H) N O_{2}

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Solution

The correct option is A $C H_{3} C H_{2} O N O$
$C H_{3} - C H_{2} - O - N = O$ is a nitrite derivative, hence it is not a nitro derivative.

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C_{6} H_{5} N O_{2} + 6 [H] S n / H C l - -------- \to X + 2 H_{2} O

X

{C H}_{3} - O - C_{6} H_{4} O H

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C_{6} H_{5} - C H_{2} - C H = C H_{2} + H B r \to

C_{6} H_{5} - C H = C H_{2} + H B r P e r o x i d e - ---- \to

1. {{(C H}_{3})}_{2} ˙ C H < {{(C H}_{3})}_{3} ˙ C < (C_{6} {H_{5})}_{2} ˙ C H < (C_{6} {H_{5})}_{3} ˙ C 2. (C_{6} {H_{5})}_{3} ˙ C < (C_{6} {H_{5})}_{2} ˙ C H < {{(C H}_{3})}_{3} ˙ C < {{(C H}_{3})}_{2} ˙ C H 3. (C_{6} {H_{5})}_{2} ˙ C H < (C_{6} {H_{5})}_{3} ˙ C < {{(C H}_{3})}_{3} ˙ C < {{(C H}_{3})}_{2} ˙ C H 4. {{(C H}_{3})}_{2} ˙ C H < {{(C H}_{3})}_{3} ˙ C < (C_{6} {H_{5})}_{3} ˙ C < (C_{6} {H_{5})}_{2} ˙ C H

C_{6} H_{6}, {C H}_{3} O H, C_{6} H_{5} {N H}_{2}

C_{6} H_{5} {N O}_{2}

80^{0} C, 65^{0} C, 184^{0} C

212^{0} C

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