The correct option is D Carbon tetrachloride+Toluene
HNO3+Water, HCl+water and Acetic acid + Pyridine are non-ideal solution showing negative deviations.
Positive deviation:
Solvent-solute interaction is less than the solvent-solvent and the solute-solute interactions
Negative deviation:
Solvent-solute interaction is more than the solvent-solvent and the solute-solute interactions.
Carbon tetrachloride + Toluene is an example of non-ideal solution showing positive deviation.