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Question

Which of the following is not an example of disproportionation reaction?

A
4ClO3Cl+3ClO4
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B
2H2O22H2O+O2
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C
2NO2+2OHNO2+NO3+H2O
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D
TiCl4+2MgTi+2MgCl2
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Solution

The correct option is D TiCl4+2MgTi+2MgCl2
Disproportionation, sometimes called dismutation, is a redox reaction in which a compound of intermediate oxidation state converts to two different compounds, one of higher and one of lower oxidation states. Thus calculating the oxidation number of each central atom by using H=+1,O=2,Cl=1
A. 4+5ClO31Cl+3+7ClO4
Its a disproportionation reaction
B. 2H21O22H22O+0O2
Its a disproportionation reaction
C. 2+4NO2+2OH+3NO2++5NO3+H2O
Its a disproportionation reaction
D. +4TiCl4+20Mg0Ti+2+2MgCl2
Its not a disproportionation reaction but its a displacement reaction.

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