The correct option is
D TiCl4+2Mg→Ti+2MgCl2Disproportionation, sometimes called dismutation, is a redox reaction in which a compound of intermediate oxidation state converts to two different compounds, one of higher and one of lower oxidation states. Thus calculating the oxidation number of each central atom by using H=+1,O=−2,Cl=−1
A. 4+5ClO−3→−1Cl−+3+7ClO−4
Its a disproportionation reaction
B. 2H2−1O2→2H2−2O+0O2
Its a disproportionation reaction
C. 2+4NO2+2OH−→+3NO−2++5NO−3+H2O
Its a disproportionation reaction
D. +4TiCl4+20Mg→0Ti+2+2MgCl2
Its not a disproportionation reaction but its a displacement reaction.