The correct option is D Pig iron
Pig iron: The iron obtained from Blast furnace
contains about 4% carbon and many impurities in smaller amount (e.g., S, P, Si, Mn). This is known as pig iron.
All others are ore.
Malachite→Cu(OH)2.CuCO3
Zinc blends→ZnS
Bauxite→Al2O3.2H2O