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Question

Which of the following is not correct regarding the adsorption of a gas on the surface of solid?

A
On increasing pressure, adsorption keeps on increasing.
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B
Enthalpy and entropy changes are negative.
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C
Chemisorption is more specific than physisorption.
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D
It is a reversible reaction.
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Solution

The correct option is A On increasing pressure, adsorption keeps on increasing.
  • The accumulation of molecular species the surface rather than in the bulk of a solid or liquid is termed adsorption.
  • The adsorption process is exothermic, the physical adsorption occurs readily at low temperature and decreases with increasing temperature. By Le-Chatelier’s principle as the pressure increases the rate of adsorption increases but as it reaches to a saturation point then it will not increases anymore.
Hence, option A is correct answer.

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