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Question

Which of the following is not expected to show paramagnetism?

A
[Ni(H2O)]2+
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B
Ni(CO)4
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C
[Ni(NH3)4]2+
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D
[Co(NH3)6]2+
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Solution

The correct option is B Ni(CO)4
Ni(CO)4 is not expected to show paramanetism due to absence of unpaired electrons.
Electronic configuration of Ni is [Ar]183d84s2.

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