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Stability of Carbocation

Which of the ...

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Which of the following is not hypovalent a. CH_3^+ b. B_2H_6 c. NH_2^+ d. AlF_{

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Q. In the given compound A,C and A,D are exbhits which of the following isomerism :

C H_{3} - C H_{2} - C H_{2} - C H_{2} N H_{2}

(1^{o})

C H_{3} - C H_{2} - N H_{2} | C H - C H_{3}

(1^{o})

C H_{3} - C H_{3} | C H - C H_{2} - N H_{2}

2-Methylpropanamine

(1^{o})

C H_{3} - C H_{3} | C | - C H_{3} N H_{2}

2-methylpropan-2-amine

(1^{o})

C H_{3} - C H_{2} - C H_{2} - N H - C H_{3}

N-methylpropanamine

(2^{o})

Q. What is the decreasing order of strength of the bases

O H^{-}, N H_{2}^{-}, H C \equiv C^{⊝}

C H_{3} - C H_{2}^{⊝}

Q. Which of the following lone-pair indicated is not involved in resonance?
(A)

C H_{2} = C H - . . N H - C H_{3}

C H_{2} = C H - . . O . . - C H_{3}

C H_{2} = C H - . . O . . - C H = C H_{2}

C H_{2} = C H - N H_{2}

Q. In the given example B,C and B,D are :

C H_{3} - C H_{2} - C H_{2} - C H_{2} N H_{2}

(1^{o})

C H_{3} - C H_{2} - N H_{2} | C H - C H_{3}

(1^{o})

C H_{3} - C H_{3} | C H - C H_{2} - N H_{2}

2-Methylpropanamine

(1^{o})

C H_{3} - C H_{3} | C | - C H_{3} N H_{2}

2-methylpropan-2-amine

(1^{o})

C H_{3} - C H_{2} - C H_{2} - N H - C H_{3}

N-methylpropanamine

(2^{o})

C H_{3} - N H | | C (1) - N H_{2}

C H_{3} - C H_{2} (2) - N H_{2}

(C H_{3})_{2} (3) N H

C H_{3} - O | | C (4) - N H_{2}

The correct order of the basicities of the following compounds is:

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