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Question

Which of the following is not peroxide?

A
NaHO2
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B
BaO2
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C
Na2O2
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D
PbO2
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Solution

The correct option is C PbO2
Here answer is option D.
PbO2 are not true peroxide because they do not liberate H2O2 on treatment with dilute acids.
Lead (1V) oxide and the lead atom shares its 4 electrons 2 each with oxygen atoms. In Peroxide there a bond sharing of two oxygen atoms as in:
Hydrogen Peroxide
HOOH

Water is an oxide
HOH

Likewise PbO2 is an oxide Pb has a valency 4
O=Pb=O

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