Which of the following is not resonating structure of each other?

C H_{3} - N = C = S

and

C H_{3} - S - C = N

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C H_{3} - + C = O

and

C H_{3} - C \equiv + O

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C H_{3} - O | | C - O H

and

C H_{3} - O^{-} | C = + O - H

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C H_{2} = C H - + C = N H

and

+ C H_{2} - C H = C = N H

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Solution

The correct option is A $C H_{3} - N = C = S$ and $C H_{3} - S - C = N$
In resonating structures, the relative positions of atoms remain the same, only the bond distribution changes. This condition is not satisfied by option $A$ . Hence, they are not resonating structures of each other.

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C H_{2} = O H | C - C H_{2} - O | | C - C H_{3} ⇌ C H_{3} - O | | C - C H_{2} - O | | C - C H_{3} ⇌ C H_{3} - O H | C = C H - O | | C - C H_{3}

I

I I

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C H_{2} = O H | C - C H_{2} (I) - O | | C - C H_{3} ⇌ C H_{3} - O | | C - C H_{2} (I I) - O | | C - C H_{3}

⇌ C H_{3} - O H | C = C H (I I I) - O | | C - C H_{3}

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I I I . C H_{3} - O | | C - ¯ C H_{2} \leftrightarrow C H_{3} -^{-} C = C H_{2}

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C H_{3} - O | | C - C H_{2} - O | | C - O - C_{2} H_{3}

C H_{3} - O H | C = C H - O | | C - O - C_{2} H_{5}

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