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Question

Which of the following is oxidised by KMnO4?

A
Methane
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B
Pentane
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C
Isobutane
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D
Neopentane
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Solution

The correct option is C Isobutane
Controlled oxidation is a process of heating the substance with a regulated supply of O2/air at high pressure, in the presence of a catalyst to produce various oxidation products.
The given reaction is a controlled oxidation reaction.
Generally, alkanes resist oxidation but alkanes having 3o H atom can be oxidized to alcohol by KMnO4
Here, Isobutane (3) is oxidised by KMnO4 to tertiary butyl alcohol.
(CH3)3CHKMnO4(CH3)3COHtertiary butyl alcohol

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