Which of the following is pseudo-unimolecular reaction?

2 H_{2} O_{2} ⟶ 2 H_{2} O + O_{2}

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C_{6} H_{5} N_{2} C l + H O H ⟶ C_{6} H_{5} O H + N_{2} + H C l

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C H_{3} C O O C_{2} H_{5} + N a O H ⟶ C H_{3} C O O N a + C_{2} H_{5} O H

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2 O_{3} ⟶ 3 O_{2}

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Solution

The correct option is D $C_{6} H_{5} N_{2} C l + H O H ⟶ C_{6} H_{5} O H + N_{2} + H C l$
In a chemical reaction if two or more reactants are involved but the rate of reaction depends only upon the concentration of one of the reactant and independent of other reactants then it is said to be a pseudo unimolecular reaction.
so the option B shows the pseudotype of reaction

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C H_{3} C O O C_{2} H_{5} + N a O H \to C H_{3} C O O N a + C_{2} H_{5} O H

K [C H_{3} C O O C_{2} H_{5}] {[N a O H]}_{+}

C H_{3} C O O C_{2} H_{5} + H_{2} O H^{+} - ----- \to C H_{3} C O O H + C_{2} H_{5} O H

C_{6} H_{5} N_{2} C l

{C u}_{2} {C l}_{2} / H C l \to

C H_{3} C O O C_{2} H_{5} + H_{2} O ⇌ C H_{3} C O O H + C_{2} H_{5} O H

2

2

C_{6} H_{5} O H + O_{3} ⟶ {C O}_{2} + H_{2} O + O_{2}

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