The correct option is C PAN
Secondary pollutants are pollutants which are formed in the atmosphere. These pollutants are not emitted directly from a source.
(a) Natural sources of CO2 include decomposition, ocean release and respiration. Human sources come from activities like deforestation as well as the burning of fossil fuels like coal, oil and natural gas etc.
(b) Source of N2O: Nitrous oxide is emitted during agricultural and industrial activities, combustion of fossil fuels and solid waste, as well as during treatment of wastewater.
(c) Peroxyacyl nitrates (PANs) is formed during the photochemical reactions of hydrocarbons in the atmosphrere. As it is formed in the atmosphere, it is a secondary pollutant. It is one of the most potent eye irritant found in photochemical smog.
(d) Source of SO2: The main sources of SO2 emissions are from fossil fuel combustion at power plants, refineries, and other industrial facilities.