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Applications of Crystallisaion

Which of the ...

Question

Which of the following is soluble in yellow ammonium sulphide ?

A

CuS

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B

CdS

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C

SnS

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D

PbS

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Solution

The correct option is C SnS
The sulfides of As³⁺, As⁵⁺, Sb³⁺, Sb⁵⁺, Sn²⁺, Sn⁴⁺are soluble in yellow ammonium sulfide where they form polysulphidecomplexes.

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Q. The II group precipitates soluble in yellow ammonium sulphide may be :

Q. Which of the following precipitate is insoluble in yellow ammonium sulphide?

{S b}_{2} S_{3}

is not soluble in yellow ammonium sulphide. Reason: The common ion effect due to

S^{2 -}

ions reduce solubility of

{S b}_{2} S_{3}

.

Q. II B (arsenic group) sulphides are soluble in yellow ammonium sulphide. If conc. HCl is added to this soluble portion, coloured precipitates are formed.
If true enter 1, else enter 0.

{A s}_{2} S_{3}

({N H}_{4})_{2} S_{2}

(yellow ammonium sulphide) due to the formation of

({N H}_{4})_{3} {A s S}_{4}

If the given statement is true enter 1 else enter 0.

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