Which of the following is the correct order of basic strength of amines in gaseous phase -

(C H_{3})_{2} N H

C H_{3} N H_{2}

(C H_{3})_{3} N

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(C H_{3})_{2} N H

(C H_{3})_{3} N

(C H_{3}) N H_{2}

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(C H_{3})_{3} N

(C H_{3})_{2} N H

C H_{3} N H_{2}

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(C H_{3})_{3} N

C H_{3} N H_{2}

(C H_{3})_{2} N H

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Solution

The correct option is C $(C H_{3})_{3} N$ > $(C H_{3})_{2} N H$ > $C H_{3} N H_{2}$
In gas phase, only inductive effect decides the basic strength of amine.

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C H_{3} N H_{2}, (C H_{3})_{2} N H, (C H_{3})_{3} N

N H_{3}

C H_{3} N H_{2}, (C H_{3})_{3} N, (C H_{3})_{2} N H

C H_{3} N H_{2}, (C H_{3})_{2} N H, (C H_{3})_{3} N, N H_{3}

Arrange the following in the decreasing order of their basic strength in aqueous solution:

$C H_{3} N H_{2}, (C H_{3})_{2} N H, (C H_{3})_{3} N$ and $N H_{3}$

Arrange the following in increasing order of their basic strength:

(i) C₂H₅NH₂, C₆H₅NH₂, NH₃, C₆H₅CH₂NH₂ and (C₂H₅)₂NH

(ii) C₂H₅NH₂, (C₂H₅)₂NH, (C₂H₅)₃N, C₆H₅NH₂

(iii) CH₃NH₂, (CH₃)₂NH, (CH₃)₃N, C₆H₅NH₂, C₆H₅CH₂NH₂.

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