Which of the following is true about the complex $[P t C l_{2} (H_{2} O) (N H_{3})]$ :

Its geometry is tetrahedron

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Platinum is

s p^{3}

hybridised

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It is paramagnetic complex

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It exhibits geometrical isomerism

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Solution

The correct option is D It exhibits geometrical isomerism
$[P t C l_{2} (H_{2} O) (N H_{3})]$
Pt-oxidation state $+ 2$ :
Valence configuration $= 5 d^{8}$
Complex is a square planar complex so diamagentic and exhibits geometrical isomerism.

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