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Question

Which of the following is true regarding stability of eclipsed and staggered conformation?

A
Eclipsed conformation is more stable than staggered conformation
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B
Eclipsed conformation is less stable than staggered conformation
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C
Stability of eclipsed and staggered conformations are equal
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D
None of the above
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Solution

The correct option is B Eclipsed conformation is less stable than staggered conformation
Option (b) is the correct answer because the dihedral angle in eclipsed conformation is 0 and in staggered conformation is 60. So, the C-H bonds are close to each other in eclipsed conformation , hence the torsoinal strain is maximum and less stable.

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