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Question

Which of the following is used to perform following transformation?

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A
SOCl2
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B
PCl5
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C
PCl3
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D
NH3
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Solution

The correct options are
A SOCl2
B PCl5
C PCl3
A carboxylic acid, RCOOH can be converted into an acyl chloride RCOCl by replacing OH with Cl using PCl5, PCl3 or SOCl2. The chloride anion produced during the reaction acts a nucleophile and attacks on the carbonyl C and forms RCOCl.

RCOOH+PCl5RCOCl+POCl3+HCl
RCOOH+PCl3RCOCl+H3PO3
RCOOH+SOCl2RCOCl+SO2+HCl

Option A, B And C are correct.

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