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Question

Which of the following method(s) is/are not used for separation of azeotropic mixtures?

A
Simple distillation
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B
Fractional distillation
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C
Distillation under reduced pressure
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D
Steam distillation
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Solution

The correct option is D Steam distillation
Distillation technique is used to separate volatile substance from non-volatile compound in a mixture i.e., they have their individual different boiling point temperature.

Azeotropic mixture is a liquid mixture of two miscible liquids which distill over without changes in composition.

These azetropic mixture boils at a same temperature rather than the boiling temperature of individual liquids.
Hence, during boiling the composition remains same.
So, azeotropic mixture are not separated by any of the distillation techniques.

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