The correct option is D Distillation
Liquation:
This method is used for the refining of metals having low melting point and are associated with high melting impurities, e.g., Pb,Sn,Sb,Bi.
Distillation:
Metals having low boiling point are refined by this method. For example, zinc, cadmium and mercury.
Electrorefining of Metals:
Metals such as Cu,Ag,Zn,Sn,Pb,Al,Ni,Cr are refined by this method.