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Question

Which of the following molecule has 3C - 4e− bond?

A
Al2Cl6
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B
Be2Cl4
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C
I2Cl6
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D
All are having 3C - 4e bond
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Solution

The correct option is D All are having 3C - 4e bond
Let us assess the options in a piecemeal manner:

Each of the bridging chlorine atoms together with the 2 aluminium atoms constitute a
3center - 4electron bond. This is true for the other two compounds as well:

The dimer of BeCl2 also has a 3c-4e bond. As is the case with I2Cl6:


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