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Question

Which of the following molecule/ion has higher B−O bond length ?

A
H3BO3
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B
[B(OH)4]
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C
Both (a) and (b) have equal BO bond length
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D
None of these
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Solution

The correct option is C [B(OH)4]
In [B(OH)4] the BO bond length is higher to minimize the repulsion between bond pairs of electrons.

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