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Question

Which of the following molecules do not have regular geometry?

A
IF5
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B
CH4
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C
BF3
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D
CCl4
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Solution

The correct option is B IF5
In IF5, Iodine makes 5 covalent bonds with fluorine, with a lone pair on Iodine. So hybridization is sp3d2 and molecular geometry is distorted octahedral due to lone pair. Its shape is square pyramidal.
So, IF5 shows Berry-Pseudorotation which is the rapid exchange of the axial and equatorial ligands.
Due to which it does not have a regular geometry.

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