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Question

Which of the following molecules has a trigonal pyramidal geometry?

A
BH3
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B
H2O
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C
CH4
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D
NH3
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E
AlCl3
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Solution

The correct option is D NH3
Option D is the correct answer.
NH3 has trigonal pyramidal geometry. Nitrogen has five electrons in its outermost shell. Of them, three are required to form three sigma bonds with three Hydrogen atoms. One lone pair still remains on the NItrogen atom. Thus, NH3 is sp3 hybridized and should have an angle of about 109o . But because of the presence of one lone pair on Nitrogen atom, its bond angle decreases to about 107o.

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