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Question

Which of the following molecules has the shortest carbon-carbon single bond length?

A
CH2=CHCCH3
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B
CH2=CHC=N
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C
CH2=CHC=O
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D
CH2=CHCH=CH2
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Solution

The correct option is C CH2=CHC=O
The bond between CO in C=O will be minimum as oxygen have higher electronegativity than carbon. The C=C bond is more likely to be added upon some reagent rather than the C=O bond. The carbonyl group is more reactive than the alkene group. Hence carbon and oxygen in carbonyl compound will be more attracted towards each other. Hence they have small bond length.

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