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Question

Which of the following molecules is/are linear?

A
ICl2
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B
IF+2
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C
OF2
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D
CdBr2
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Solution

The correct options are
B ICl2
D CdBr2
In ICl2, I form sigma bonds and have three lone pair, it's hybridisation is sp3d in which lone pairs are placed in equatorial position and sigma bonds are formed along with axial position which gives it linear structure.

In CdBr2 , Cd forms 2 sigma bonds and have 0 lone pair, it's hybridisation is sp and thus is linear in shape.

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