Which of the following not only decolourises alkaline potassium permanganate but also gives red precipitate with ammoniacal cuprous chloride solution ?
A
Ethane
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B
Methane
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C
Ethene
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D
Acetylene
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Solution
The correct option is D Acetylene CH≡CH+ Cu2Cl2 + NH4OH→ + Cu−C≡C−Cu + NH4Cl + 2H2O
C2H2 acetylene is an alkyne and thus forms precipitate with ammonical cuprous chloride solution. Also alkynes decolourises alkaline potassium permanganate solution.