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Question

Which of the following option are correct for [Fe(CN)6]3 complex?
(a) d2sp3 hybridisation
(b) sp3d2 hybridisation
(c) Paramagnetic
(d) Diamagnetic

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Solution

According to VBT, the molecular orbital electronic configuration of Fe3 in [Fe(CN)6]3 is



Hybridisation = d2sp3
Number of unpaired electron =1
Magnetic property= Paramagnetic
Hence, correct choices are options (a) and (c).


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