The correct option is D 6f
Number of spherical nodes =n−l−1
For 2s orbital, the number of spherical nodes =2−0−1=1
For 4s orbital, the number of spherical nodes =4−0−1=3
For 3d orbital, the number of spherical nodes =3−2−1=0
For 6f orbital, the number of spherical nodes =6−3−1=2