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Question

Which of the following orders are correct for first ionization potentials?

A
Ba < Sr < Ca
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B
Ga < Tl < B
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C
C < O < N
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D
Mg < Al < Si
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Solution

The correct options are
A Ba < Sr < Ca
B Ga < Tl < B
C C < O < N

I.E. generally decreases down the group
B > Tl > Ga This is because of the poor shielding of d and fe
N > O > C This is because of the extra stability of half-filled atomic orbitals in N.


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