Which of the following orders are correct for first ionization potentials?
A
Ba < Sr < Ca
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B
Ga < Tl < B
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C
C < O < N
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D
Mg < Al < Si
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Solution
The correct options are ABa < Sr < Ca BGa < Tl < B CC < O < N
→I.E. generally decreases down the group B > Tl > Ga → This is because of the poor shielding of d and f−e− N > O > C →This is because of the extra stability of half-filled atomic orbitals in N.