Which of the following orders is not correct regarding the −I effect of the substituents?
A
−SR<−OR<−+OR2
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B
−+NR2<−OR<−F
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C
−I<−Cl<−Br<−F
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D
−+NR2<−+OR2<−F
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Solution
The correct option is C−I<−Cl<−Br<−F Decreasing order of −I power of groups with respect to reference H is: −NH2<−OR<−OH<−I<−Br<−Cl<−F<−−COOR<−CHO<−NO2