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Question

Which of the following orders regarding the boiling point of halogens is true?

A
HF> HCI> HBr >HI
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B
HF< HCI< HBr <HI
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C
HF> HCI< HBr <HI
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D
HF> HCI> HBr <HI
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Solution

The correct option is C HF> HCI< HBr <HI
HF has the maximum ionic due to the largest electronegative difference between H and F and there is H-bonding.
HCl, HBr, and HI are polar covalent.

The boiling point of covalentα Molarmass
HI > HBr > HCl
Since the boiling point of ionic > covalent
HF > HCl < HBr < HI

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