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Question

Which of the following pair is isostructural?

A
XeF2 and IF2
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B
NH3 and BF3
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C
CO23 and SO23
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D
PCl5 and ICl5
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Solution

The correct option is A XeF2 and IF2

XeF2 and IF2 are isostructural. Both have sp3d-hybridization and linear structure.There are 2 bond pairs and 3 lone pairs of electrons,which occupy all the 3 equatorial positions.


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