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Question

Which of the following pair/s have nearly same size?

A
Zr, Hf
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B
Nb, Ta
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C
Fe, Zn
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D
K, Rb
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Solution

The correct options are
A Zr, Hf
B Nb, Ta
Due to lanthanide contraction, the size of second and third transition series are nearly same. It is due to increase in nulcear charge by 32 units except for Y and La.
ZrHf, NbTa

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