The correct option is C CO, CO2
The law of multiple proportions say that If two elements form more than one compound between them, then the ratios of the masses of the second element which combine with a fixed mass of the first element will be ratios of small whole numbers. The ratio of the masses of oxygen that can react with 100 grams of carbon is 266:133, i.e. 2:1, a ratio of small whole numbers in CO and CO2.