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Question

Which of the following pairs has the same size?

A
Fe2+,Zn2+
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B
Zr4+,Ti4+
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C
Zr4+,Hf4+
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D
Zn4+,Hf4+
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Solution

The correct option is B Zr4+,Hf4+
Zr4+ and H4+ belong to group IVB. But, H4+ has same size as Zr4+ due to the addition of 14 lanthanide elements before in which electrons are added into the f-subshell which poorly shield the outer electrons and contraction in size occurs.

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