Which of the following pairs is-are correctly matched-I- Carbocation - electrophileII- Free radical - paramagneticIII- Carbene - incomplete octetIV- Carbanion - incomplete octetSelect the correct answer using the codes given below-

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Free Radical

Which of the ...

Question

Which of the following pairs is/are correctly matched?

I. Carbocation $\Leftrightarrow$ electrophile

II. Free radical $\Leftrightarrow$ paramagnetic

III. Carbene $\Leftrightarrow$ incomplete octet

IV. Carbanion $\Leftrightarrow$ incomplete octet

Select the correct answer using the codes given below:

Only I

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I and II

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I, II, III and IV

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I, II and III

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Solution

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[C o (N H_{3})_{5} (N O_{2})] C l_{2}

[C o (N H_{3})_{5} (O N O) C l_{2} . . . (L i n k a g e)

[C u (N H_{3})_{4}] [P t C l_{4}]

[P t (N H_{3})_{4}] [C u C l_{4}] . . . (C o o r d i n a t i o n)

[P t C l_{2} (N H_{3})_{4}] B r_{2}

[P t B r_{2} (N H_{3})_{4}] C l_{2} . . . (I o n i z a t i o n)

The correct order for decreasing stability of the following free radicals is

(I) N i (C O)_{4}

(I I) F e (C O)_{5}

(I I I) V (C O)_{6}

(I V) C r (C O)_{6}

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