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Question

Which of the following pairs is/are functional isomers?

A
butan-2-ol and ethoxy ethane
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B
ethanal and vinyl alcohol
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C
acetaldehyde and acetone
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D
ethanoic acid and methyl formate
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Solution

The correct options are
A butan-2-ol and ethoxy ethane
B ethanal and vinyl alcohol
D ethanoic acid and methyl formate
Functional isomers have the same molecular formula but the different functional group.
A) butan-2-ol and ethoxyethane: CH3CH(OH)CH2CH3 and C2H5OC2H5; secondary alcohol and ether groups.
B)
ethanal and vinyl alcohol: CH3CHO and CH2=CHOH; aldehyde and alcohol groups.
C)
acetaldehyde and acetone: CH3CHO and CH3COCH3; aldehyde and ketone groups but with different molecular formula.
D) ethanoic acid and methyl formate: CH3COOH and HCOOCH3; carboxylic acid and ester group.

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