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Question

Which of the following pairs of complexes are isomeric with each other but their aqueous solutions exhibit different molar conductivities?


A

[PtCl2(NH3)4]Br2 and [PtBr2(NH3)4](OH)2

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B

[Pt(OH)2(NH3)4]SO4 and [PtSO4(NH3)4](OH)2

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C

K3[Fe(CN)2] and K4[Fe(CN)6]

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D

[Co(NH3)5Br]SO4 and [Co(NH3)5SO4]CI

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Solution

The correct option is B

[Pt(OH)2(NH3)4]SO4 and [PtSO4(NH3)4](OH)2


[Pt(OH)2(NH3)4]SO4[Pt(OH)2(NH3)4]+2+SO24

[PtSO4(NH3)4](OH)2[PtSO4(NH3)4]+2+2OH

The complexes are ionization isomers, as they differ in number of ions and they have different molar conductivities due to different number of ions.


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