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Question

Which of the following pairs of ions are isoelectronic and isostructural?

A
SO23,NO3
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B
ClO3,CO23
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C
CO23,NO3
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D
ClO3,SO23
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Solution

The correct option is C CO23,NO3
Isostructural chemical compounds have similar chemical structures.
Isoelectronic terms refer to two-atom, ions or molecules that have the same number of valence electrons.

Number of electrons

CO23=6+2+24=32

SO23=16+2+24=42

ClO23=17+24+1=42

NO3=7+1+24=32

Hence CO23 and NO3 are isoelectronic and trigonal planar in shape.

Option C is correct.

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