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Question

Which of the following pairs of isomers will rotate the plane polarised light in exactly equal amounts (same magnitude) but in opposite directions?

A
Diastereomer
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B
Enantiomer
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C
Cis-trans isomer
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D
None of these
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Solution

The correct option is B Enantiomer
Enantiomers are non-superimposable mirror images and they are optically active.
Enantiomers will rotate the plane of polarisation in exactly equal amounts (same magnitude) but in opposite directions.
Dextrorotary designated as (+) gives clockwise rotation (to the right) while leavorotatory designated as (-), gives anti-clockwise rotation (to the left).
Hence option b is correct.

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