The correct options are
B (1,3)
D (2,7)
(2,4)→ set of two different even numbers can never be coprime as they have common factors 1 and 2.
(1,3)→ yes they are coprime because every natural number is coprime with 1.
(3,6)→ not coprime because they have common factors 1 and 3.
(2,7)→ yes they are coprime because they have only one common factor i.e. 1.
Note: Set of two different prime numbers are always coprime to each other.