The correct option is A Ca2+,S2−
Isoelectronic ions are ions that have the same number of electrons. Atomic no. of Ca is 20. Ca2+ has lost two electrons Therefore it has 18 electrons. Atomic no. of S is 16. S2− has gained two electrons. Therefore, it has 18 electrons. Hence, Ca2+ and S2− are isoelectronic ions.