Which of the following pairs represents linkage isomers?

[C u (N H_{3})_{4}] [P t C l_{4}]

and

[P t (N H_{3})_{4}] [C u C l_{4}]

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[P t C l_{2} (N H_{3})_{4}] B r_{2}

and

[P t B r_{2} (N H_{3})_{4}] C l_{2}

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[C o (N H_{3})_{5} N O_{3}] S O_{4}

and

[C o (N H_{3})_{5} S O_{4}] N O_{3}

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[P d (P P h_{3})_{2} (N C S)_{2}]

and

[P d (P P h_{3})_{2} (S C N)_{2}]

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Solution

The correct option is D $[P d (P P h_{3})_{2} (N C S)_{2}]$ and $[P d (P P h_{3})_{2} (S C N)_{2}]$
$S C N^{-}$ is an ambidentate ligand.

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