The correct option is
D AgNO3 solution and copper metal.Metal above in activity series are more reactive and can displace the less reactive metal.
(a) NaCl solution and copper metal
Na is more reactive than Cu, thus it will not give diplacement reaction.
(b) MgCl2 solution and aluminium metal.
Al can not replace Mg because it is lower on the reactivity series.
(c) FeSO4 solution and silver metal
Ag can not replace Fe because it is lower on the reactivity series.
(d) AgNO3 solution and copper metal.
Ag can be replaced by Cu as it is above silver in the reactivity series. Therefore, this pair will give displacement reaction.
AgNO3+Cu→Cu(NO3)2+Ag
Hence, option D is correct.