Dear Student,
(a) Copper wire and acetic acid solution at 250 oC. [This is because the conductance of a metal decreases with increase in temperature whereas for electrolyte like acetic acid it increases with increase in temperature.]
(b) Copper wire at 250 oC and copper wire at 500 oC. [The reason is stated above]
(b) 0.1 M acetic acid solution or 1M acetic acid solution. [The conductance increases with increase in concentration of the solution, as more number of ions will participate in the conduction process.]
Best Wishes !