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Question

Which of the following pentahalides of Bi exists:

A
BiCl5
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B
BiBr5
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C
BiI5
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D
BiF5
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Solution

The correct option is D BiF5
BiF5 exist but BiCl5, BiBr5 and BiF5 does not probably due to strong oxidising properties of B and also due to inert pair effect.

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