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Question

Which of the following possesses highest melting point?

A
p-dichlorobenzene
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B
m-dichlorobenzene
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C
Chlorobenzene
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D
o-dichlorobenzene
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Solution

The correct option is A p-dichlorobenzene
Molecules with better packing​ in crystal form have higher melting points. In general​, molecules with high symmetry​ has better packing efficiency in crystal lattice​ than molecules with​
low symmetry. ​p-dichlorobenzene molecule has symmetrical structure and it can fit well in its crystal lattice. The intermolecular forces of attraction are strong. Hence, it possesses highest melting point among given options.
Hence, option (a) is the correct answer.

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