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Question

Which of the following process does not occur during the formation of CHCl3 from C2H5OH and CaOCl2?

A
Hydrolysis
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B
Oxidation
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C
Reduction
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D
Chlorination
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Solution

The correct option is C Reduction
Chloroform is prepared in the laboratory by heating a mixture of bleaching powder (CaCl2) with ethanol. In this reaction bleaching powder acts as an oxidising, chlorinating and hydrolysing agent.
CH3CH2OH+[O]CH3CHO+H2O Oxidation
CH3CHO+3Cl2CCl3CHO+3HCl Chlorination
2CCl3CHO+Ca(OH)22CHCl3+Ca(COOH)2 Hydrolysis

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